Model studies on the ring construction of the auriside macrolactone |
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Authors: | Rodolfo Tello-Aburto |
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Institution: | Division of Medicinal and Natural Products Chemistry, The University of Iowa, Iowa City, IA 52242, United States |
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Abstract: | The preparation of a 12-membered ring macrolactone model of auriside that contains a pendant diene chain bearing a bromide was investigated employing two approaches. The first approach utilized an oxidative rearrangement of a tertiary allylic alcohol on a 12-membered ring. The second approach was based on a 1,4-methylation of an ynone followed by macrolactonization. |
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