A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using Mo(CO)6 |
| |
| Authors: | Annamalai Senthilvelan Wen-Sheng Chung |
| |
| Institution: | a Department of Applied Chemistry, National Chiao-Tung University, Hsinchu 30050, Taiwan, ROC
b Instrumentation Center, National Taiwan University, Taipei 106, Taiwan, ROC |
| |
| Abstract: | The Mo(CO)6-mediated photoinduced ring-opening reactions of adamantane isoxazolines involve novel rearrangement that provide enaminoketones as major products and β-hydroxy ketones as minor ones; in contrast, only β-hydroxy ketones and α,β-unsaturated ketones were obtained under thermal condition. |
| |
| Keywords: | Adamantane isoxazolines Photorearrangement Isomerization Enaminoketones |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
