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Synthesis of the first deprotected indigo N-glycosides (blue sugars) by reductive glycosylation of dehydroindigo |
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| Authors: | Martin Hein Dirk Michalik Michael Lalk |
| Institution: | a Institut für Chemie, Universität Rostock, Albert-Einstein-Strasse 3a, D-18059 Rostock, Germany b Institut für Biochemie, Universität Greifswald, Soldmannstr. 16, D-17487 Greifswald, Germany c Leibniz-Institut für Katalyse e.Van der Universität Rostock, Albert-Einstein-Strasse 29a, D-18059 Rostock, Germany d Institut für Anorganische und Analytische Chemie, Universität Jena, August-Bebel-Str. 2, D-07740 Jena, Germany e Institut für Pharmazie, Universität Greifswald, Ludwig-Jahn-Str. 17, D-17487 Greifswald, Germany |
| Abstract: | The first deprotected indigo N-glycosides (blue sugars) have been prepared by reaction of dehydroindigo with in situ generated rhamnosyl, glucosyl and mannosyl iodide. |
| Keywords: | Dehydroindigo Indigo N-Heterocycles Regioselectivity |
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