Synthesis, characterization and photoluminescent properties of platinum complexes with novel bis(imidazoline) pincer ligands |
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| Authors: | Xin-Qi Hao Chen-Xia Du |
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| Affiliation: | Department of Chemistry, Henan Key Laboratory of Chemical Biology and Organic Chemistry, Zhengzhou University, Zhengzhou 450052, PR China |
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| Abstract: | Chiral C2-symmetric bis(imidazoline) pincer ligands 2a-d have been synthesized for the first time. Direct cycloplatination of these ligands with K2PtCl4 in dry acetic acid afforded the corresponding cycloplatinated pincer complexes 3a-d. The X-ray single-crystal structure of platinum complex 3d and the preliminary studies on the photoluminescent properties of 3 are reported. |
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| Keywords: | 1,3-Bis(2&prime -imidazolinyl)phenyl Chiral Platinum Pincer complexes Photoluminescent |
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