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Polymer-supported monodentate phosphite ligands for asymmetric hydrogenation
Authors:Weiping Chen  Stanley M. Roberts  John Whittall
Affiliation:StylaCats Ltd, Chemistry Department, University of Liverpool, Liverpool L69 7ZD, UK
Abstract:
Several new polymer-supported monophosphite ligands have been developed and the rhodium complexes were shown to be highly efficient, highly enantioselective and easily separable catalysts for asymmetric hydrogenation of itaconates, enamides, α-dehydroamino acid derivatives and β-dehydroamino acid derivatives.
Keywords:Polymer-supported   Monodentate ligands   Phosphites   Asymmetric hydrogenation
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