Polymer-supported monodentate phosphite ligands for asymmetric hydrogenation |
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Authors: | Weiping Chen Stanley M. Roberts John Whittall |
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Affiliation: | StylaCats Ltd, Chemistry Department, University of Liverpool, Liverpool L69 7ZD, UK |
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Abstract: | ![]() Several new polymer-supported monophosphite ligands have been developed and the rhodium complexes were shown to be highly efficient, highly enantioselective and easily separable catalysts for asymmetric hydrogenation of itaconates, enamides, α-dehydroamino acid derivatives and β-dehydroamino acid derivatives. |
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Keywords: | Polymer-supported Monodentate ligands Phosphites Asymmetric hydrogenation |
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