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Novel diapocarotenoid dications with VIS/NIR absorption
Authors:Geir Kildahl-Andersen
Institution:Department of Chemistry, Norwegian University of Science and Technology (NTNU), NO-7491 Trondheim, Norway
Abstract:Isoprenoid acyclic polyene carbodications with 6, 14 and 18 π electrons have been synthesized and characterized in comparison with previously prepared dicyclic C40-carotenoid dications. An equation correlating λmax (400-1100 nm region) and the number of sp2 hybridized carbon atoms in the dication is presented.
Keywords:Acyclic C10  C20 and C24 diapocarotenoid dications  Preparation  VIS/NIR-correlation
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