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Tuning the oxidation properties of vanadium(V) through ligand stoichiometry |
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| Authors: | Wei Zeng |
| Institution: | Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA |
| Abstract: | Vanadium(V) (5 mol %) and hydroxamic acid ligand (45 mol %) were found to promote the selective tert-butyl hydroperoxide-mediated oxidation of allylic and propargylic alcohols to the corresponding aldehydes and ketones. |
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