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Formation of chiral charge-transfer complex with axially chiral 1,1′-bi-2-naphthol and viologen derivatives |
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| Authors: | Yoshitane Imai Takafumi Kinuta Nobuo Tajima Yoshio Matubara |
| Institution: | a Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, Kowakae, Higashi-Osaka 577-8502, Japan b JST ERATO-SORST Kuroda Chiromorphology Team, 4-7-6, Komaba, Meguro-ku, Tokyo 153-0041, Japan c First-Principles Simulation Group, Computational Materials Science Center, NIMS, Sengen, Tsukuba, Ibaraki 305-0047, Japan d Department of Life Sciences, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8902, Japan |
| Abstract: | By using three types of viologen derivatives, we synthesized chiral charge-transfer (CT) complexes with an axially chiral 1,1′-bi-2-naphthol molecule and successfully controlled the crystal structure and inclusion ability of the third component by changing the viologens. |
| Keywords: | Chiral CT complex 1 1&prime -Bi-2-naphthol Viologen |
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