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ortho Substituent effect on a 1,5-H shift reaction during thermal decomposition of aryltriazenes
Authors:Michael Harmata  Xuechuan Hong  Pinguan Zheng
Affiliation:Department of Chemistry, University of Missouri-Columbia, Columbia, MO 65211, United States
Abstract:
An ortho substituent group has a significant effect on thermal decomposition of aryltriazenes. When the ortho methoxy-substituted phenyltriazenes were treated with methyl iodide at 110-130 °C, 1,5-H shift products were obtained in fair to moderate yields.
Keywords:
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