Rhodium(I) catalyzed decomposition of formic acid |
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| Authors: | SH Strauss KH Whitmire DF Shriver |
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| Institution: | Department of Chemistry, Northwestern University, Evanston, Illinois 60201 U.S.A |
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| Abstract: | Rh(C6H4PPh2)(PPh3)2 catalyzes the decomposition of formic acid to CO2 and H2. The initial step is the oxidative addition of formic acid to produce the intermediate Rh(HCO2)(PPh3)3, which probably is followed by β-hydride elimination, to produce CO2 and RhH(PPh3)3. The latter reacts with formic acid to produce H2 and to reform Rh(HCO2)(PPh3)3. |
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