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IR study of aqueous metal perchlorate solutions
Authors:J. Stangret  J. Kostrowicki
Affiliation:(1) Department of Physical Chemistry, Institute of Inorganic Chemistry and Technology, Technical University of Gda"nacute"sk, 80-952 Gda"nacute"sk, Poland;(2) Department of General Chemistry, Institute of Inorganic Chemistry and Technology, Technical University of Gda"nacute"sk, 80-952 Gda"nacute"sk, Poland
Abstract:
Aqueous solutions of Mn(II), Co(II), Ni(II), and Zn(II) perchlorates, and for comparison, Mg(II) and Ca(II) perchlorates, have been studied by IR spectroscopy using HDO as an indicator. The investigations were carried out over the entire available concentration range of these salts. Computer deconvolution of the measured spectra demonstrates the effect of metal cations on the HDO molecules.
Keywords:Manganese, cobalt, nickel, zinc, magnesium and calcium perchlorate  aqueous solutions  infrared spectra  isotopic dilution method  deconvolution of spectra  OD groups
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