Titanosilicates as Supports for an Enzymatic Alcoholysis Reaction |
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| Authors: | Fá tima Nunes Serralha, José Madeira Lopes, Francisco Lemos, Duarte Prazeres, Maria Aires-Barros, Joo Rocha, Joaquim Cabral Fernando Ramô a Ribeiro |
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| Affiliation: | (1) Chemistry Section, Central Mechanical Engineering Research Institute, Durgapur, 713209, India;(2) Chemistry Section, Jadavpur University, Calcutta, 700032, India |
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| Abstract: | ![]()
Novel [CrIII(amp)(bipy)(Cl)] (1) (H2amp = N-(hydroxyphenyl)salicyldimine; bipy = 2,2 -bipyridyl) and [CrIII(app)(bipy)(Cl)]+ (2) (H2app = N-(hydroxyphenyl)pyridine-2-carboxaldimine; bipy = 2,2-bipyridyl) complexes have been synthesized and characterized by physico-chemical methods. Complexes 1 and 2 have been employed as catalysts in the oxidation of both saturated and unsaturated hydrocarbons using tert-butylhydroperoxide (t-BuOOH). The significance of the results with respect to oxo-functionalization of C-H bonds both in unsaturated and saturated hydrocarbons is noted. |
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| Keywords: | Oxo transfer catalysis chromium complexes t-BuOOH cyclohexene cyclohexane toluene |
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