Molecular structure of (±)-5-benzylamino-endo-tricylo[5.2.1.02,6]dec-4-en-3-one |
| |
| Authors: | René de Gelder Jan M. M. Smits Frank J. A. D. Bakkeren Antonius J. H. Klunder |
| |
| Affiliation: | 1. Department of Inorganic Chemistry, Nijmegen SON Research Center, University of Nijmegen, Toernooiveld 1, 6525 ED, Nijmegen, The Netherlands
2. Department of Organic Chemistry, Nijmegen SON Research Center, University of Nijmegen, Toernooiveld 1, 6525 ED, Nijmegen, The Netherlands
|
| |
| Abstract: | The crystal and molecular structure of (±)-5-benzylamino-endo-tricyclo[5.2.1.02.6]dec-4-en-3-one is described. The X-ray analysis revealed that the reduction of the norbornene double bond is an important process in the irradiation of the used enaminones. The structure was solved by direct methods and refined by least squares methods toR 1=0.0468 for 2070 reflections (withI>2σ(I). Crystal data: C17H19NO, Orthorhombic, space groupPbcn, a=40.695 (1),b=6.6928 (1),c=10.2378(4)Å,V=2788.44(14)Å3,Z=8. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
