Highly efficient 1,4-addition of 1,3-diesters to conjugated enones by In/TMSCl |
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| Authors: | Lee Phil Ho Seomoon Dong Lee Kooyeon Heo Yunkiu |
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| Affiliation: | Department of Chemistry, Kangwon National University, Chunchon 200-701, Republic of Korea. phlee@kangwon.ac.kr |
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| Abstract: | ![]()
Organoindium reagents derived from indium and diethyl bromomalonates were added to a wide range of conjugated enones in a 1,4-fashion in the presence of TMSCl under mild conditions, and corresponding oxo-1,3-diesters were obtained in good to excellent yields. |
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