Palladium-catalyzed aminocarbonylation of aryl iodides using aqueous ammonia |
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| Authors: | Tongyu Xu Howard Alper |
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| Affiliation: | Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada |
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| Abstract: | ![]()
Aminocarbonylation of aromatic iodides using aqueous ammonia in toluene has been developed. Various primary aromatic amides have been efficiently synthesized in good to excellent yields in the presence of catalytic quantities of Pd(OAc)2/CYTOP®292. The usage of aqueous ammonia avoids the handling of two gases in the reaction. |
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| Keywords: | Palladium Aminocarbonylation Aqueous ammonia Aryl iodide |
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