|
|||||
|
|
Facile synthesis of C-phosphanylformamidines via a carbene pathway |
|
| Authors: | Anatoliy Marchenko Georgyi KoidanAnastasiya Hurieva Aleksandr SavateevAleksandr Kostyuk |
| Affiliation: | Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Murmanska 5, Kyiv-94 02660, Ukraine |
| Abstract: | A direct synthetic approach to C-phosphanyl-N,N-dialkyl-N′-aryl(alkyl)-formamidines was developed. It was shown that phosphorylation of the formamidines proceeds at the nitrogen atom affording N-phosphanylformamidinium salts. Upon deprotonation, these salts gave C-phosphanylformamidines via formation of carbenes followed by a 1,2-phosphorus shift. |
| Keywords: | C-Phosphanylformamidines N-Phosphanylformamidinium triflates Phosphanylation Deprotonation |
| 本文献已被 ScienceDirect 等数据库收录！ | |