The first bowl-shaped stable neutral radical with a corannulene system: synthesis and characterization of the electronic structure |
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| Authors: | Morita Yasushi Nishida Shinsuke Kobayashi Tadahiro Fukui Kozo Sato Kazunobu Shiomi Daisuke Takui Takeji Nakasuji Kazuhiro |
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| Affiliation: | Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. morita@chem.sci.osaka-u.ac.jp |
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| Abstract: | ![]()
[structure: see text] A bowl-shaped neutral radical with a corannulene system has been designed and synthesized for the first time as a stable solid in air. An unequivocal characterization of the electronic properties of the radical shows that an appreciable amount of spin delocalization extends onto the corannulene unit's curved surface. |
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