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Metal anodes oxidation rate forecasted by results of electrolysis
Authors:V. A. Kovrov  A. P. Khramov  N. I. Shurov  Yu. P. Zaikov
Affiliation:1.Institute of High-Temperature Electrochemistry, Ural Branch,Russian Academy of Sciences,Yekaterinburg,Russia
Abstract:This work represented the results from electrolysis tests of low-melting cryolite-alumina melts at temperatures of 790 and 850°C using metal anodes based on Cu-Fe-Ni and Cu-Al. The duration of experiment was at least 72 h. With these results, oxide layer dissolution/erosion rate and anodic material oxidation depth was calculated in arbitrary units (alloy cm/year) with examples of extrapolated (forecasted) experimental data of oxidation depth and oxide layer thickness for a long period. The oxide layer formed on the anode surface by electrolysis of the studied materials was found to decelerate further oxidation all over the period of tests.
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