Metal anodes oxidation rate forecasted by results of electrolysis |
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Authors: | V. A. Kovrov A. P. Khramov N. I. Shurov Yu. P. Zaikov |
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Affiliation: | 1.Institute of High-Temperature Electrochemistry, Ural Branch,Russian Academy of Sciences,Yekaterinburg,Russia |
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Abstract: | This work represented the results from electrolysis tests of low-melting cryolite-alumina melts at temperatures of 790 and 850°C using metal anodes based on Cu-Fe-Ni and Cu-Al. The duration of experiment was at least 72 h. With these results, oxide layer dissolution/erosion rate and anodic material oxidation depth was calculated in arbitrary units (alloy cm/year) with examples of extrapolated (forecasted) experimental data of oxidation depth and oxide layer thickness for a long period. The oxide layer formed on the anode surface by electrolysis of the studied materials was found to decelerate further oxidation all over the period of tests. |
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