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Self‐Assembly of Organic Chromosphere Cations with Inorganic Lanthanide(III) Complex Counterions
Authors:Dandane Li  Xianshun Sun  Nanqi Shao  Jieying Wu  Yupeng Tian
Affiliation:Department of Chemistry, Key Laboratory of Functional Inorganic Materials, Chemistry of Anhui Province, Anhui University, Hefei, P. R. China
Abstract:
Hybrid complexes based on a D‐π‐A type dye p‐aminostyryl‐pyridinum cation and a lanthanide(III) complex anion were synthesized by ionic exchange reaction. Different alkyl‐substituted amino groups were used as electron donors in organic dye cations. The synthesized complexes were characterized by elemental analysis. In addition, the structural features of them were studied by single‐crystal X‐ray diffraction analysis. Their optical properties were systematically investigated by absorption and fluorescence spectroscopy.
Keywords:Hybrid complexes  Lanthanide(III) complex  Ion exchange  X‐ray diffraction  Optical properties
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