The first synthesis of a methano[60]fullerene with an electron-donating group at the methano-bridge carbon: synthesis and reaction of aminomethano[60]fullerene |
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| Authors: | Tada Tomoyuki Ishida Yasuhiro Saigo Kazuhiko |
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| Institution: | Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. |
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| Abstract: | reaction: see text] Aminomethano60]fullerene was synthesized for the first time as a trifluoromethanesulfonic acid salt by applying the Curtius rearrangement of azidocarbonylmethano60]fullerene as the key reaction. Aminomethano60]fullerene thus obtained was found to be able to react with various acyl chlorides to afford the corresponding amides. |
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