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Evaluation of the bond energy terms for the various types of boron-nitrogen bonds
Authors:G. Leroy  M. Sana  C. Wilante
Affiliation:(1) Laboratoire de Chimie Quantique, Bâtiment Lavoisier, Place Louis Pasteur, 1, Bte 35, B-1348 Louvain-la-Neuve, Belgium;(2) National Fund for Scientific Research, Belgium
Abstract:
Summary We have determined a series of bond energy terms in compounds containing dative, single, double and/or triple boron-nitrogen bonds. We describe various interesting applications based on these bond energy terms namely the determination of enthalpies of atomization and stabilization energies. More particularly, the conventional ring strain energies of three- and four-membered small ring containing boron and nitrogen atoms could be determined and the aromaticity of borazine, reexamined.Dedicated to Professor Alberte Pullman
Keywords:Boron-nitrogen bonds  Enthalpies of atomization  Stabilization energies  Aromaticity of borazine
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