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Totalsynthese des macrodiolids (r,r)-(−)-grahamimycin a1 |
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| Authors: | Hans-Jü rgen Bestmann,Rainer Schobert |
| Affiliation: | Institut für Organische Chemie der Universität Erlangen Nürnberg Henkestraβe 42, D-8520, Erlangen, Germany |
| Abstract: | The title compound is synthesized by use of the easily accessible aldehyde for establishing both chiral centres and of ketenylidentriphenylphosphorane for cyclization. In contrast to literature our product is not an antibiotic. |
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