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Radiolysis of alkyl benzene sulfonat (ABS) in aqueous solution
Institution:1. DST-CSIR National Centre for Nanostructured Materials, Council for Scientific and Industrial Research, Pretoria 0001, South Africa;2. Department of Applied Chemistry, University of Johannesburg, Doornfontein 2028, South Africa;1. Department of Medical & Biological Engineering, Kyungpook National University, Daegu 41944, Republic of Korea;2. Institute of Biomedical Engineering Research, Kyungpook National University, Daegu 41944, Republic of Korea;3. Institute of New Drug Research, Korea University Sejong Campus, 2511, Sejong-ro, Sejong City 30019, Republic of Korea;4. Department of R&D center, Myungmoon Bio Co., Hwaseong, Gyeonggi-do 18622, Republic of Korea;5. Department of Chemistry, College of Natural Science, Kyungpook National University, Daegu 41944, Republic of Korea;6. Department of Radiology, School of Medicine, Kyungpook National University, Daegu 41944, Republic of Korea;7. Laboratory Animal Center, Daegu-Gyeongbuk Medical Innovation Foundation, Daegu 41061, Republic of Korea;8. Department of Molecular Medicine, School of Medicine, Kyungpook National University, Daegu 41944, Republic of Korea;9. Department of Radiology, Kyungpook National University Hospital, Daegu 41944, Republic of Korea;1. Department of Radiology, All India Institute of Medical Sciences, New Delhi 110029, India;2. Department of Gastroenterology, All India Institute of Medical Sciences, New Delhi, India;3. Department of Biostatistics, All India Institute of Medical Sciences, New Delhi 110029, India;1. Department of Chemistry, Panjab University, Chandigarh 160014, India;2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russia;3. Novosibirsk State University, 2 Pirogova Str., 630090 Novosibirsk, Russia;1. Department of Analytical Chemistry, China Pharmaceutical University, Nanjing 210009, China;2. Key Lab Modern Toxicology (NJMU), Ministry of Education, Department of Hygienic Analysis and Detection, School of Public Health, Nanjing Medical University, Nanjing 211166, China;3. Key Laboratory of Drug Quality Control and Pharmacovigilance, Ministry of Education, China Pharmaceutical University, Nanjing 210009, China
Abstract:Degradation of alkyl benzene sulfonate (ABS) in aerated aqueous solution irradiated with gamma radiation with doses up to 1.8 kGy were studied. The degree of degradation, pH change, the effect of pH on the degradation, COD values and the degradation products were determined. The degradation of ABS increases with the increase of doses and decreases with the increase of ABS concentration. The degradation was somewhat more efficient in slightly acidic and neutral solutions than at basic pH oxalic acid was detected by HPLC as degradation product.
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