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Densities and viscosities for ionic liquids mixtures containing [eOHmim][BF4], [bmim][BF4] and [bpy][BF4]
Affiliation:1. Department of Petroleum Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran;2. Department of Petroleum Engineering, Ahwaz Faculty of Petroleum, Petroleum University of Technology, Ahvaz, Iran
Abstract:Densities and viscosities of binary ionic liquids mixtures, 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate ([eOHmim][BF4]) + 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]), 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate ([eOHmim][BF4]) + N-butylpyridinium tetrafluoroborate ([bpy][BF4]) and 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) + N-butylpyridinium tetrafluoroborate ([bpy][BF4]) were measured over the entire mole fraction from T = (298.15 to 343.15) K. The excess molar volumes were calculated and correlated by Redlich–Kiser polynomial expansions. The viscosities for pure ionic liquids were analyzed by means of the Vogel–Tammann–Fulcher equation and ideal mixing rules were applied for the ILs mixtures.
Keywords:Ionic liquids mixtures  Density  Excess property  Viscosity
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