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Production of electrically conductive, core/shell polystyrene/polyaniline composite particles by chemical oxidative seeded dispersion polymerization
Authors:M. Okubo  S. Fujii  H. Minami
Affiliation:(1) Department of Chemical Science and Engineering, Faculty of Engineering Kobe University, Rokko, Nada Kobe 657, Japan e-mail: okubo@cx.kobe-u.ac.jp Tel.: +81-78-8036161; Fax: +81-78-8036205, JP
Abstract:Micron-sized, monodispersed, electrically conductive polystyrene (PS)/polyaniline (PAn) composite particles were produced by chemical oxidative seeded dispersion polymerization of aniline at 0 °C with 1.37-μm-sized, monodispersed PS seed particles in HCl aqueous solution, where the pH value was kept at 2.5 with a pH stat. The composite particles consisted of a PS core and a PAn shell. A pellet of the composite particles had a conductivity of 3.4 × 10−3 S/cm. Received: 5 April 2000 Accepted: 10 August 2000
Keywords:Aniline  Electrically conductive  Core/shell morphology  Chemical oxidative seeded dispersion polymerization  Micron size
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