| Coordination Triangular Prism of Bisilver Complex with Triply—bridged of Bis（diphenylphosphino）amine |
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| 引用本文： | 施林熙,张礼仪,陈忠宁.Coordination Triangular Prism of Bisilver Complex with Triply—bridged of Bis（diphenylphosphino）amine[J].结构化学,2003,22(3):283-286. |
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| 作者姓名： | 施林熙 张礼仪 陈忠宁 |
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| 作者单位： | State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
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| 基金项目： | This work was supported by NNSFC (No. 20171044) and the project for "undred Talents from" the Chinese Academy of Sciences |
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| 摘 要： | 1 INTRODUCTION Recently coinage metal complexes of poly- dentate phosphines are of great interest owing to the applications in diverse areas such as supramolecular design, photophysics and catalysis1～4]. It is well- known that the binuclear coinage metal complexes of diphosphine M2(diphosphine)2(MeCN)2]2+ (M = Cu, Ag, Au)5～16] are excellent precursors for the design of polynuclear or polymeric materials with desired properties due to the easy substitution of weakly coordinated ac…
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| 关 键 词： | 正三棱柱 银配合物 桥联 双（二苯膦基）胺 晶体结构 [Ag2（μ－Ph2PNHPPh2）3]（ClO4）2.CH2Cl2.CH3OH 表征 |
Coordination Triangular Prism of Bisilver Complex with Triply-bridged of Bis(diphenylphosphino)amine |
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| Abstract: | The binuclear complex Ag2(m-Ph2PNHPPh2)3](ClO4)2CH2Cl2CH3OH (Ph2PNHP- Ph2 = bis(diphenylphosphino)amine) was prepared from the reaction of AgClO4 with bis- (diphenylphosphino)amine in equimolar ratio through self-assembly. The coordination cation affords a triply-bridging Ag2L3]-type coordination moiety. The silver atom is in a trigonal planar environment with P3 coordination chromophore. The complex (C74H69Cl4N3O9P6Ag2) crystallizes in monoclinic, space group Cc with a = 18.3738(1), b = 20.0207(4), c = 20.5422(4) ? b = 95.829(1), V = 7517.5(2) 3, Z = 4, Mr = 1687.68, Dc = 1.491 g/cm3, F(000) = 3432, m = 0.848 mm-1, the final R = 0.0460 and wR = 0.0935 for 7005 observed reflections with I > 2s(I). |
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| Keywords: | bis(diphenylphosphino)amine binuclear complex crystal structure silver |
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