The dipole moments and molecular structure of chloral and bromal hydrates |
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| Affiliation: | Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore-12 India;Harbin Institute of Technology Shenzhen Graduate School, Shenzhen Key Laboratory of Water Resource Utilization and Environmental Pollution Control, Shenzhen 518055, China |
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| Abstract: | The dipole moment of chloral hydrate is 2·07 D and 2·65 D at 35° in benzene and dioxane solutions respectively. Bromal hydrate has a moment of 2·56 D in benzene solution. The moments observed can reasonably be accounted for on the scheme of Smith et al. and the results have been discussed in terms of the possible structures of these molecules. |
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