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Semi-empirical relation between freezing point and critical point properties of a wide variety of molecular liquids
Abstract:
Based on experimental data for some 28 freezing liquids, we define a semi-empirical relation connecting surface tension and molar volume with the molar critical volume. It is shown that the semi-empirical equation deduced by means of this relation allows one to calculate the given critical property for various molecular liquids with high accuracy.
Keywords:freezing liquids  energy balance  molar critical volume
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