Epoxidation of Bicyclo[2.2.1]hept-5-ene-2,3-endo- and Exodicarboxylic Acid N-Arylimides |
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| Authors: | Salakhov M S Bagmanova M I |
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| Institution: | (1) Institute of Polymer Materials, Azerbaidzhanian National Academy of Sciences, Sumgait, 373204, Azerbaidzhan |
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| Abstract: | Epoxidation of endo- and exo-bicyclo2.2.1]hept-5-ene-2,3-dicarboxylic acid N-arylimides with a solution of peracetic acid in anhydrous dioxane affords 5,6-exo-epoxybicycloheptanedicarboxylic acid N-arylimides. The epoxidation reaction is not sensitive to the configuration of the imide fragment, to the character and position of the substituent in the aromatic ring. The reaction is determined only by oxidation conditions. |
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