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Separation of Phenolic Compounds and Organic Anions Using ODS Column Coated with Meso-octamethylcalix[4]pyrrole and Water as Eluent
作者姓名:LiJunHE  ShiJunSHAO  YongGUO  HuaJiaoMA  XiaLIU  ShengXiangJIANG
作者单位:LanzhouInstituteofChemicalPhysics,ChineseAcademyofSciences,Lanzhou730000
摘    要:Octadecylsilanized silica (ODS) was coated with meso-octarnethylcalix4]pyrrole to obtain a novel calix4]pyrrole containing stationary phase for HPLC. Compared to ODS, the new stationary phase showed a relatively large retention and an improved separation for phenolic compounds and organic anions, using pure water as mobile phase. The results can be ascribed to the interaction between analytes and calix4]pyrrole.

关 键 词:分离  酚化合物  有机阴离子  ODS  涂层柱  内消旋八甲基杯[4]吡咯    洗提液  HPLC  八癸基硅

Separation of Phenolic Compounds and Organic Anions Using ODS Column Coated with Meso-octamethylcalix[4]pyrrole and Water as Eluent
LiJunHE ShiJunSHAO YongGUO HuaJiaoMA XiaLIU ShengXiangJIANG.Separation of Phenolic Compounds and Organic Anions Using ODS Column Coated with Meso-octamethylcalix[4]pyrrole and Water as Eluent[J].Chinese Chemical Letters,2003,14(9):946-947.
Authors:Li Jun He  Shi Jun SHAO  Yong GUO  Hua Jiao MA  Xia LIU  Sheng Xiang JIANG
Abstract:Octadecylsilanized silica (ODS) was coated with meso-octamethylcalix4]pyrrole to obtain a novel calix4]pyrrole containing stationary phase for HPLC. Compared to ODS, the new stationary phase showed a relatively large retention and an improved separation for phenolic compounds and organic anions, using pure water as mobile phase. The results can be ascribed to the interaction between analytes and calix4]pyrrole.
Keywords:Meso-octamethylcalix[4]pyrrole  coated-column  phenolic compounds  anions  HPLC  
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