| 单次碰撞条件下NH2(A2A1,(0,9,0))转动非弹性碰撞 |
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| 引用本文： | 董峰,邹胜利,陈宏,李学初,楼南泉.单次碰撞条件下NH2(A2A1,(0,9,0))转动非弹性碰撞[J].物理化学学报,1999,15(9):812-818. |
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| 作者姓名： | 董峰 邹胜利 陈宏 李学初 楼南泉 |
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| 作者单位： | State Key Laboratory of Molecular Reaction Dynamics,Dalian Institute of Chemical Physics,Chinese Academic of Sciences,Dalian 116023 |
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| 基金项目： | 国家攀登计划，自然科学基金资助项目 |
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| 摘 要： | 在单次碰撞条件下 ,对NH2 (～A2 A1,(0 ,9,0 ) )的转动非弹性碰撞进行了详细的研究 ,包括不同转动能级、核自旋、及自旋分裂双重态的传能 ,直接得到了一些倾向性规则 ,并且对于能隙规律和角动量传递规律在其中的重要性作了初步探讨
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| 关 键 词： | 转动态-态传能 NH2 倾向性规则 能隙规律 角动量传递规律 |
| 收稿时间： | 1999-01-22 |
| 修稿时间： | 1999-04-12 |
Rotational Inelastic Collisions of NH2(A2A1,(0,9,0)) under Single Collisional Condition |
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| Dong Feng,Zou Shengli,Chen Hong,Li Xuechu,Lou Nanquan.Rotational Inelastic Collisions of NH2(A2A1,(0,9,0)) under Single Collisional Condition[J].Acta Physico-Chimica Sinica,1999,15(9):812-818. |
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| Authors: | Dong Feng Zou Shengli Chen Hong Li Xuechu Lou Nanquan |
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| Institution: | State Key Laboratory of Molecular Reaction Dynamics,Dalian Institute of Chemical Physics,Chinese Academic of Sciences,Dalian 116023 |
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| Abstract: | The study on the rotational state to state energy transfer (RSET) of asymmetric top molecule NH 2 (～A2A1) (0,9,0) under molecular beam condition is reported in detail, including a systematic study of the relative population transferred as functions of initially excited quantum state, different Ka, nuclear-spin, and even spin-doublet. Some propensity rules were obtained directly, and the relation of the mechanism of RSET with EGL (energy gap law) and AMT(angular momentum transfer) was discussed. |
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| Keywords: | NH_2 rotational state to state energy transfer Propensity rule Energy gap law Angular momentum transfer |
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