Fabrication of novel multilayered thin films based on inclusion complex formation between amylose derivatives and guest polymers |
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Authors: | Kida Toshiyuki Minabe Takashi Nakano Suguru Akashi Mitsuru |
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Institution: | Department of Applied Chemistry, Graduate School of Engineering, Osaka Univesity, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan. |
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Abstract: | Novel types of layer-by-layer (LbL) assembly films were successfully fabricated onto a solid substrate through the inclusion complex formation between partially 2,3- O-methylated amyloses (MAs) and polytetrahydrofuran (PTHF). The formation of the LbL assembly films was confirmed by quartz crystal microbalance (QCM) analysis, atomic force microscopy (AFM) observation, and X-ray diffraction (XRD) measurement. The film formation was significantly affected by the methylation degree of amylose. When MAs with 8 and 20% methylation were used as hosts, the formation of LbL assembly films with PTHF was clearly observed. On the other hand, MAs with more than 33% methylation barely formed LbL assembly films with PTHF. |
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