Bond models for the photochemical reactivity of transition metal complexes |
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Authors: | Claudio Furlani |
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Institution: | 1. Istituto di Chimica, Università di Roma, Roma, Italia
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Abstract: | Weakening of σ bonds along the labilized axis in the lowest excited quartet state of Cr(III) complexes as estimated through σ-bond orders in a simple MO-LF model, is consistent with substitution of the stronger ligand via a mechanism initiated by a predissociative step. |
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