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| Asymmetric Synthesis of N-（Diphenylphosphinyl）furfurylamine by the Enantioselective Alkylation of Furfurylimine | |
| 引用本文： | Hai Le ZHANG Xiao Mei ZHANG Xin LI Ai Qiao MI Xin CUI Yao Zhong JIANG. Asymmetric Synthesis of N-（Diphenylphosphinyl）furfurylamine by the Enantioselective Alkylation of Furfurylimine[J]. 中国化学快报, 2005, 16(9): 1147-1150 |
| 作者姓名： | Hai Le ZHANG Xiao Mei ZHANG Xin LI Ai Qiao MI Xin CUI Yao Zhong JIANG |
| 作者单位： | [1]Key Laboratory of Asymmetric Synthesis and Chirotechnology of Sichuan Province and Union Laboraotry of Asymmetric Synthesis, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041 |
| 摘 要： | Optically active N-（diphenylphosphinyl）furfurylamines 2 with good ee values were obtained by the enantioselective addition of dialkylzincs to furfuryl imine 1 in the presence of chiral aminoalcohol derivatives and oxazolines. |
| 关 键 词： | 唑啉 手性化合物 衍生物 糠基 |
| 收稿时间： | 2004-10-18 |
Asymmetric Synthesis of N-(Diphenylphosphinyl)furfurylamine by the Enantioselective Alkylation of Furfurylimine |
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| Hai Le ZHANG,Xiao Mei ZHANG,Xin LI,Ai Qiao MI,Xin CUI,Yao Zhong JIANG. Asymmetric Synthesis of N-(Diphenylphosphinyl)furfurylamine by the Enantioselective Alkylation of Furfurylimine[J]. Chinese Chemical Letters, 2005, 16(9): 1147-1150 | |
| Authors: | Hai Le ZHANG Xiao Mei ZHANG Xin LI Ai Qiao MI Xin CUI Yao Zhong JIANG |
| Abstract: | Optically active N-(diphenylphosphinyl)furfurylamines 2 with good ee values were obtained by the enantioselective addition of dialkylzincs to furfuryl imine 1 in the presence of chiral aminoalcohol derivatives and oxazolines. |
| Keywords: | Asymmetric dialkylzinc N-(diphenylphosphinyl)furfurylamine |
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