| 氧化酶及烷烃氧化 |
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| 引用本文： | 姜标,伍登熙,左亚军,郜莉,李祖义.氧化酶及烷烃氧化[J].有机化学,2007,26(2):209-217. |
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| 作者姓名： | 姜标 伍登熙 左亚军 郜莉 李祖义 |
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| 作者单位： | 1. 中国科学院上海有机化学研究所,上海,200032
2. 上海华谊集团公司,上海,200025 |
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| 摘 要： | 记述了氧化酶在生物催化中的应用. 较之传统的化学反应, 氧化还原生物催化反应有较好的选择性、可控性和经济性, 人们正在积极地寻找这类催化剂. 自然界中被高度还原的烃类品种丰富, 因此催化烷烃末端或近末端氧合反应的酶也相对容易找到. 很多这一类的酶生化特性已作了详细的描述, 烷烃加氧酶催化高附加值反应的潜力已得到了广泛地认可.
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| 关 键 词： | 氧化酶 烷烃 羟化酶 |
| 收稿时间： | 2006-6-5 |
| 修稿时间： | 2006-06-05 |
Oxygenases and Oxygenation of Alkanes |
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| JIANG Biao,WU Deng-Xi,ZUO Ya-Jun,GAO Li,LI Zu-Yi.Oxygenases and Oxygenation of Alkanes[J].Chinese Journal of Organic Chemistry,2007,26(2):209-217. |
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| Authors: | JIANG Biao WU Deng-Xi ZUO Ya-Jun GAO Li LI Zu-Yi |
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| Institution: | 1. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032;2. Shanghai Huayi Company, Shanghai 200025 |
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| Abstract: | This article describes oxidising enzymes used for biocatalytic applications. Redox biocatalysts are highly sought after because of the selectivity, controllability and economy of their reactions, in compari- son with conventional chemical reactions. As highly reduced hydrocarbons are abundant in the environment, enzymes that catalyze the terminal or subterminal oxygenation of alkanes are relatively easy to find. A number of these enzymes have been biochemically characterized in detail, because the potential of alkane hydroxylases to catalyze high added-value reactions was widely recognized. |
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| Keywords: | oxygenase alkane hydroxylase |
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