STRUCTURE AND MAGNETIC PROPERTIES OF LaCo13-BASED ALLOYS |
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Institution: | Institute of Physics, Academia Sinica, Beijing 100080, China |
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Abstract: | The structure and magnetic properties of two series of LaCois-based alloys, LaCo13-xFex(0≤x≤6) and La1-xRx(Co, Fe)13 (x=0.1,0.2; R=Y, Ge, Pr, Nd Sm, Gd, Tb, Dy, Ho, Er, and Yb), are studied by X-ray diffraction and magnetic mea- surements. In the above-mentioned composotions, all the samples display a structure of NaZn13 type (space group: Fm3c). In LaCo13-xFex system, as the iron content increases, its Curie temperature decreases, while thc magnetic moment per 3d atom increases. This may be explained by a rigid band model. In the other alloy system, the Curie temperature goes through a maxium at R=Gd, and this reflects the influ- ence of R - T interaction. It is also observed that saturation magnetization varies with R and gets lower when R is a heavy rare earth element. The contribution of R is close to that of a free-ion moment. La0.9Pr0.1Co9Fe4 has the largest value 29$\mu$B/f.u. |
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