Superconductivity in Alkali-Doped C60 |
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Authors: | Ming-Liang ZHANG Han-Ying GUO |
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Institution: | Institute of Theoretical Physics, Academia Sinica, P. O. Box 2735B, Beijing 100080, China |
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Abstract: | There ark three kinds of effective attractive interaction between C602- and "nearly free" electron in A3C60: 1) the strong short-range attraction between the low energy unoccupied orbital of C602- ions and the "nearly free" electrons; 2) the potential barrier due to large angular momentum of t1u orbital; 3) the A+ crystal field forced "nearly free" electrons in C602- neighborhood. All effective attraction coupling with the A+ optical modes and the vibration modes of C60 mass center produces a strong electron-phonon interaction. It plays a principal role for A3C60 superconductivity. Based upon this mechanism critical temperature and other properties of superconductivity state can be explained by means of the BCS theory. |
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