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Crystallographic report: The [bis(η5‐cyclopentadienyl)titanium(IV)‐bis(L‐methionine)] dichloride |
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| Authors: | Radim Bína Ivana Císařová Martin Pavlišta Ivan Pavlík |
| Affiliation: | 1. Research Centre “New Inorganic Compounds and Advanced Materials”, University of Pardubice, Nam. Cs. Legii 565, 532 10 Pardubice, Czech Republic;2. Charles University, Faculty of Natural Sciences, Hlavova 2030, Albertov 6, 128 43 Prague, Czech Republic |
| Abstract: | The structure of ionic complex [Cp2Ti(L -Met)2]2+[Cl−]2 (where Cp = η5-C5H5) possessing C2 symmetry is presented. Discrete cationic units with distorted tetrahedral geometry around the central titanium atom are connected through intermolecular H···Cl bonds between ammonium group protons of α-amino acid ligands and chloride anions. Copyright © 2004 John Wiley & Sons, Ltd. |
| Keywords: | titanocene dichloride α ‐amino acids |