Diene complexes of early transition metals: ideas and progresses at Osaka University |
| |
Authors: | Akira Nakamura Kazushi Mashima |
| |
Institution: | a OM Research, 7-2-1308, Minami-ohgimachi, Kita-ku, Osaka 530-0052, Japan b Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan |
| |
Abstract: | Historical perspectives for the chemistry of diene complexes of early transition metals developed at Osaka University in the period after 1970s were reviewed briefly and personally. Preparative chemistry of this field commenced from the magnesium-diene 1:1 compounds and quickly extended to almost all the early transition metals. By the studies operated together with other researchers, unique features of these diene complexes, especially their bonding and structure, selective reactions, and catalysis performances are described. |
| |
Keywords: | Diene Early transition metal Group 2 metals Lanthanide metals Polymerization |
本文献已被 ScienceDirect 等数据库收录! |
|