Abstract: | The reaction products of the oxide sulphates of rare earths with hydrogen chloride are mixtures of chlorides MIIICl3 and chloride-sulphates MIIICl3 and chloride-sulphates MIIIClSO4. By oxidation of these mixtures, oxide sulphates MO2SO4 are formed as final products. Intermediary products are mixtures of MIIIOCl? MIIIClSO4. |