Thermal hazards evaluation of cumene hydroperoxide mixed with its derivatives |
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| Authors: | J.-J. Peng S.-H. Wu H.-Y. Hou C.-P. Lin C.-M. Shu |
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| Affiliation: | (1) Department of Safety, Health, and Environmental Engineering, National Yunlin University of Science and Technology, NYUST, 123, University Rd., Sec. 3, Douliou, Yunlin, 64002, Taiwan, ROC;(2) Doctoral Candidate, Graduate School of Engineering, National Yunlin University of Science and Technology, NYUST, 123, University Rd., Sec. 3, Douliou, Yunlin, 64002, Taiwan, ROC;(3) Department of Occupational Safety and Health, Jen-Teh Junior College of Medicine, Nursing and Management, 1, Jen-Teh Rd., Houlong, Miaoli, 35664, Taiwan, ROC; |
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| Abstract: | Over 90% of the cumene hydroperoxide (CHP) produced in the world is applied in the production of phenol and acetone. The additional applications were used as a catalyst, a curing agent, and as an initiator for polymerization. Many previous studies from open literature have verified and employed various aspects of the thermal decomposition and thermokinetics of CHP reactions. An isothermal microcalorimeter (thermal activity monitor III, TAM III), and a thermal dynamic calorimetry (differential scanning calorimetry, DSC) were used to resolve the exothermic behaviors, such as exothermic onset temperature (T 0), heat power, heat of decomposition (ΔH d), self-heating rate, peak temperature of reaction system, time to maximum rate (TMR), etc. Furthermore, Fourier transform infrared (FT-IR) spectrometry was used to analyze the CHP products with its derivatives at 150 °C. This study will assess and validate the thermal hazards of CHP and incompatible reactions of CHP mixed with its derivatives, such as acetonphenone (AP), and dimethylphenyl carbinol (DMPC), that are essential to process safety design. |
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| Keywords: | Cumene hydroperoxide (CHP) Fourier transform infrared (FT-IR) spectrometry Phenol Isothermal microcalorimeter (thermal activity monitor III, TAM III) Thermal dynamic calorimetry (differential scanning calorimetry, DSC) |
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