Calorimetric study and thermal analysis of crystalline nicotinic acid |
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Authors: | Wang S X Tan Z C Di Y Y Xu F Wang M H Sun L X Zhang T |
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Institution: | (1) Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, P.R. China |
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Abstract: | As one primary component of Vitamin B3, nicotinic acid pyridine 3-carboxylic acid] was synthesized, and calorimetric study and thermal analysis for this compound
were performed. The low-temperature heat capacity of nicotinic acid was measured with a precise automated adiabatic calorimeter
over the temperature rang from 79 to 368 K. No thermal anomaly or phase transition was observed in this temperature range.
A solid-to-solid transition at T
trs=451.4 K, a solid-to-liquid transition at T
fus=509.1 K and a thermal decomposition at T
d=538.8 K were found through the DSC and TG-DTG techniques. The molar enthalpies of these transitions were determined to be
Δtrs
H
m=0.81 kJ mol-1, Δfus
H
m=27.57 kJ mol-1 and Δd
H
m=62.38 kJ mol-1, respectively, by the integrals of the peak areas of the DSC curves.
This revised version was published online in August 2006 with corrections to the Cover Date. |
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Keywords: | adiabatic calorimetry heat capacity TG-DTG DSC phase transition nicotinic acid |
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