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Sunlight assisted solvent free synthesis of tert-butylperesters
Authors:Raju Singha  Prasenjit Shit
Institution:1. Department of Chemistry, Panskura Banamali College (Autonomous), Panskura R. S, India rajusingha70@gmail.com;3. Department of Chemistry, Panskura Banamali College (Autonomous), Panskura R. S, India
Abstract:Abstract

A green and efficient methodology has been developed for the direct conversion of aryl aldehydes to the corresponding tert-butyl peresters. The reaction has been carried out in absence of any solvent and the sunlight is used as the green source of energy. In this reaction tetrabutylammonium iodide (TBAI) acts as the mild organo catalyst and tert-butyl hydroperoxide (TBHP) serve as the source of tert-butyl group.
Keywords:Sunlight  Solvent free reaction  TBHP  TBAI  tert-butylperester
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