Long-range effects on palladium deposited on Pt(1 1 1) |
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| Institution: | 1. Ontario Ministry of the Environment and Climate Change, 125 Resources Road, Toronto, ON M9P 3V6, Canada;2. Great Lakes Institute for Environmental Research, University of Windsor, 401 Sunset Avenue, Windsor, ON N9B 3P4, Canada;3. Ontario Ministry of the Environment and Climate Change, 119 King Street West, 9th Floor, Hamilton, ON L8P 4Y7, Canada |
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| Abstract: | Two-dimensional long-range effects have been pointed out electrochemically for palladium adlayers on Pt(1 1 1) in the absence of anion specific adsorption. The observation of these effects requires well ordered electrode substrates. In this way, the characteristic features are not observed on stepped electrodes with 20 atoms wide terraces. The formation of a homogeneous adlayer is also required and the effects are pointed out only when the palladium coverage is close to the completion of the full monolayer. |
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