| 一氯甲酸甲酯二-三苯基膦合铂络合物晶体结构、分子结构的研究 |
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| 引用本文： | 王凤山,樊玉国,丛秋滋.一氯甲酸甲酯二-三苯基膦合铂络合物晶体结构、分子结构的研究[J].高等学校化学学报,1984,5(5):699. |
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| 作者姓名： | 王凤山 樊玉国 丛秋滋 |
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| 作者单位： | 1. 吉林大学;
2. 中国科学院兰州化物所 |
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| 摘 要： | 本文确立一氯甲酸甲酯二-三苯基膦合铂络合物是浅黄透明晶体,属于单斜晶系,P21/n空间群.并测定了晶胞参数.分子式为PtP(C6H5)3)]2·COOCH3Cl,该化合物是配位键结合的新型络合物.
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| 收稿时间： | 1983-04-27 |
The Research on the Crystal Structure of the Complex of Platinum Di (Triphenylphosphine) Methyl Formate Chloride |
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| Wang Fengshan,Fan Yuguo,Cong Qiuzi.The Research on the Crystal Structure of the Complex of Platinum Di (Triphenylphosphine) Methyl Formate Chloride[J].Chemical Research In Chinese Universities,1984,5(5):699. |
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| Authors: | Wang Fengshan Fan Yuguo Cong Qiuzi |
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| Institution: | 1. Jilin University, Changchun;
2. The Lanzou Chemistry and Physios Institute, The Chinese Acedemy of Sciences, Lanzhou |
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| Abstract: | The crystal is light yellow and transparent. It belongs to space group P21/n of monoclinic system with unit cell constants a = 12.239(6)Å, b = 23.697(8)Å, c = 12.802(5)Å, β=113.86(2)°, V = 3396(1) Å3 ,F(000) = 1548 (e), Z = 4 and has a formula of PtCP(C6H5)3]2 COOCH3 Cl. A final consistency factor R=0.0692(Rw = 0.0519) was given by the block-diagonal least-squares refinement for the crystal structure. The result of structure analysis shows that this new complex consists of two triphenylphosphines, me methyl formate and one chlorine atom bonded by coordinate bonds. |
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