Computer optimization of separation in gas-solid chromatography,optimization model and computer-modified mapping procedure |
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Authors: | Xie Minggao Zhou Chunfeng Yang Xiaohong Ding Gongyou |
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Institution: | (1) Department of Chemistry, South-Central Institute for National Minorities, 430074 Wuhan, People's Republic of China |
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Abstract: | Summary This paper proposes an optimization model for gas-solid chromatographic separations in a non-linear programming form and an approximate equation of the plate height for the model. A computer-modified mapping procedure is also described for searching the optimum separation conditions. Just five experiments and about 20 minutes of the computer time are needed to establish the optima of column temperature and of the carrier gas linear velocity. The relative deviation between the predicted and the experimental values was found to be within 20% for the plate heights, and within 1.5% for the retention times. |
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Keywords: | Gas chromatography Optimization of gas-solid separations Plate height equation Computer mapping procedure |
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