Morphology of solution crystallized trans-1,4-polyisoprene |
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Authors: | P. N. Chaturvedi M. J. Patel K. C. Patel R. D. Patel |
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Affiliation: | (1) Department of Chemistry, Sardar Patel University, India;(2) Present address: Materials Science Centre, Indian Institute of Technology, Kharagpur, India |
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Abstract: | The film formation method has been successfully used to grow single crystals and other complex morphological features of low melting form (LMF) and high melting form (HMF) of trans-1,4-polyisoprene (TPIP). Below 40 °C dilute amyl acetate solution gave hexagonal shaped LMF crystals. Thick and elongated hexagonal shaped morphology was shown by HMF crystals at temperatures above 40 °C. Straight faces and sharp corners of the single crystals, and also of complex crystals, acquired round shapes when highly polydispersed TPIP was used for crystallization. |
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Keywords: | Morphology crystallization singlecrystal trans-1 4-polyisoprene |
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