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Morphology of solution crystallized trans-1,4-polyisoprene
Authors:P. N. Chaturvedi  M. J. Patel  K. C. Patel  R. D. Patel
Affiliation:(1) Department of Chemistry, Sardar Patel University, India;(2) Present address: Materials Science Centre, Indian Institute of Technology, Kharagpur, India
Abstract:The film formation method has been successfully used to grow single crystals and other complex morphological features of low melting form (LMF) and high melting form (HMF) of trans-1,4-polyisoprene (TPIP). Below 40 °C dilute amyl acetate solution gave hexagonal shaped LMF crystals. Thick and elongated hexagonal shaped morphology was shown by HMF crystals at temperatures above 40 °C. Straight faces and sharp corners of the single crystals, and also of complex crystals, acquired round shapes when highly polydispersed TPIP was used for crystallization.
Keywords:Morphology  crystallization  singlecrystal  trans-1  4-polyisoprene
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