The 3B1-1A1 band system of sulfur dioxide: Rotational analysis of the (010), (100), and (110) bands

The (010)-(000) band of the ${}^3\text{B}{}_1\text{←}{}^1\text{A}{}_1$ system of sulfur dioxide has been rotationally analyzed and constants for the magnetic interactions in the (010) vibrational level determined. Partial rotational analyses are given for the rotationally perturbed (100)-(000) and (110)-(000) bands of the system. The extensive perturbations in this band system are provisionally attributed to: (i) vibronic interaction with a ³A₂ state, visible (a) as a large negative anharmonicity in higher bands of the ³B₁ system, and (b) as a ΔK = 0 resonance perturbation in low-lying vibrational levels of the ³B₁ state; and (ii) a K, K ± 1N-dependent perturbation possibly due to rotational-electronic coupling with a ³B₂ state, though evidence on this point is incomplete. Evidence bearing on these conclusions is discussed.