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Synthesis and structural characterisation of a novel tris-methylene bridged compound (NO) 4Fe2 Se(μ-CH2)3 |
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| Authors: | Pradeep Mathur Bala Manimaran Md. Munkir Hossain Arnold L. Rheingold Louise M. Liable-Sands Glenn P.A. Yap |
| Affiliation: | aDepartment of Chemistry, Indian Institute of Technology, Powai, Bombay 400 076, India bDepartment of Chemistry, University of Delaware, Newark, DE 19716, USA |
| Abstract: | The tris-methylene bridged compound (NO)4Fe2Se(μ-CH2)3 has been isolated. It has been characterised by IR and 1H, 13C, and 77Se NMR spectroscopy. Its structure has been determined by single-crystal X-ray diffraction methods. The structure consists of a heavy atom triangle consisting of one Se and two Fe atoms. The Fe-Fe and the two Fe-Se edges are bridged by methylene groups. |
| Keywords: | Chalcogen Alkylidene clusters |
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