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Polymer matrix of polyethylene porous films functionalized by electrical discharge plasma
Authors:I. Nová  k,I. Chodá  k,M. &Scaron  teviar,N. Saprykina,A. Kleinová  
Affiliation:a Polymer Institute, Slovak Academy of Sciences, Dúbravská cesta 9, 84236 Bratislava, Slovak Republic
b Institute of Macromolecular Compounds, Russian Academy of Sciences, 199004 St. Petersburg, Russian Federation
c Institute of Macromolecular Chemistry AS CR, v. v. i., Heyrovsky sq. 2, 16206 Prague, Czech Republic
Abstract:The polyethylene porous films were treated by dielectric surface barrier discharge (DSBD) plasma at atmospheric pressure in oxygen (O2) or nitrogen (N2), and by radio-frequency discharge (RFD) plasma in air at reduced pressure 46 Pa. The surface energy of films was carried out by direct measurements of contact angles of six testing liquids. The strength of adhesive joints in the system modified polyethylene porous films - polyacrylate was measured by peeling of the joints under the angle of 90°. The significant increase of the surface energy and its polar component of polyethylene porous films modified by all types of plasma were observed. The higher strengths of adhesive joints were found for modification of polyethylene porous films by radio-frequency discharge plasma in comparison with modification of the films by barrier discharge plasma.
Keywords:Surface modification   Polyethylene   Dielectric barrier discharge   Plasma   Surface energy   Peel strength
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